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- W1979460912 abstract "The tautomeric equilibrium between anthrone and anthranol has been shown to play an important role in the photochemistry of this system. The triplet—triplet spectrum of anthranol shows a maximum at 430 nm, while the triplet state of anthrone resembles typical aromatic ketones with λmax ≈ 580 nm. Anthrone undergoes apparent self-quenching which results from the transfer of the triplet energy from excited anthrone to anthranol. Triplet anthrone can be quenched efficiently by typical triplet quenchers such as oxygen, ditert-butylnitroxide and conjugated dienes, e.g. from 1,3-octadiene kq = 6.8 × 109M−1S−1 in benzene at 27 °C. The behaviour and spectral properties of triplet anthranol resemble those of anthracenes." @default.
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- W1979460912 date "1982-01-01" @default.
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- W1979460912 title "Laser flash studies of the photochemistry of anthrone" @default.
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- W1979460912 doi "https://doi.org/10.1016/0047-2670(82)87038-x" @default.
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