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- W1979469097 abstract "The didemnin class of biologically active cyclodepsipeptides, isolated from a marine tunicate, has shown antitumor, antiviral, and immunosuppressive activities. Synthetic studies were undertaken to prepare a modified analog of one of the most potent congeners, didemnin B (1). The side chain of the isostatine unit was tethered into the macrocycle via a cyclohexane ring in order to provide a more rigid conformation and determine the importance of this unit in bioactive compounds. This modification created a new macrocycle core and generated a diastereomeric mixture of a constrained analog of didemnin B (2)." @default.
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- W1979469097 date "1996-01-01" @default.
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- W1979469097 title "Synthetic Routes to a Constrained Ring Analog of Didemnin B" @default.
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- W1979469097 doi "https://doi.org/10.1021/jo951693i" @default.
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