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- W1979492788 abstract "The first highly enantioselective α-fluorination of ketones using organocatalysis has been accomplished. The long-standing problem of enantioselective ketone α-fluorination via enamine activation has been overcome via high-throughput evaluation of a new library of amine catalysts. The optimal system, a primary amine functionalized Cinchona alkaloid, allows the direct and asymmetric α-fluorination of a variety of carbo- and heterocyclic substrates. Furthermore, this protocol also provides diastereo-, regio-, and chemoselective catalyst control in fluorinations involving complex carbonyl systems." @default.
- W1979492788 created "2016-06-24" @default.
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- W1979492788 date "2011-01-19" @default.
- W1979492788 modified "2023-09-30" @default.
- W1979492788 title "Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones" @default.
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- W1979492788 doi "https://doi.org/10.1021/ja111163u" @default.
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