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- W1979508748 abstract "Abstract In order to obtain comonomers for the free-radical polymerization of acrylic or vinylic monomers, cyclic disufides were synthesized. Ester or amide functions were introduced in these cyclic molecules in order to afford easily degradable centers in the copolymers chains. Looking for disulfide esters or disulfide amides from commercial materials, we have selected the synthesis of ten-membered cyclic disulfide-containing diamides and diesters. As it could be expected, competitive oligomerization - by step-growth polymerization - was observed in the synthetic course but some of the so-obtained oligomers could be also suitable comonomers for our purpose. The cyclic disulfide diesters or diamides and their oligomers were separated and characterized. Owing to their higher solubility in organic solvents and monomers, disulfide diesters afford the most convenient comonomers." @default.
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- W1979508748 date "1998-12-01" @default.
- W1979508748 modified "2023-10-01" @default.
- W1979508748 title "SYNTHESIS OF CYCLIC FUNCTIONALIZED DISULFIDES AND THEIR OLIGOMERS" @default.
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- W1979508748 doi "https://doi.org/10.1080/10426509808045500" @default.
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