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- W1979510052 abstract "The evolution of the effective radii of alkali-metals and pseudo-alkali-metals (K, ...) as a function of ionicity is discussed. In agreement with the hypothesis of Shannon and Prewitt, these radii are seen to be practically independent of ionicity for the alkali-metals. Thallium(I) distinguishes itself by an evolution of the effective radius as a function of ionicity for a given coordination number. The relatively abundant structural data for the halogen compounds ABX3, A4BX6, A2BX4 … (X = Cl, Br, I; A = bulky alkali-metal or pseudo-alkali-metal; B = +2 transition element) have enabled the determination of the T1I effective radius for a given coordination number and ionicity fA-X, and the establishment of an ionicity-effective radius diagram for this cation. This diagram forms a coherent set which enables the calculation “a priori” of Tl-X interatomic distances in different compounds by the application of the rule of addition of effective radii stated by Shannon and Prewitt for oxides and fluorides." @default.
- W1979510052 created "2016-06-24" @default.
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- W1979510052 date "1986-07-01" @default.
- W1979510052 modified "2023-09-23" @default.
- W1979510052 title "Ionicity-effective radius diagram of T1I" @default.
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- W1979510052 doi "https://doi.org/10.1016/0022-4596(86)90201-x" @default.
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