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- W1979544605 abstract "For many-electron atoms, the generalized electron-pair density function g(q;a,b) represents the probability density function for the magnitude |ari+brj| of two-electron vector ari+brj to be q, where a and b are real-valued parameters. It is pointed out that the second moments 〈q2〉(a,b), associated with g(q;a,b), are related with several physical properties such as the diamagnetic susceptibility χd, the form factor F(μ), the incoherent scattering function S(μ), the minus first moment M−1 of the oscillator strength density, and the dipole polarizability α. The corresponding moments 〈t2〉(a,b) in momentum space are connected with the mass polarization correction εM, the first moment M1 of the oscillator strength density, and the nuclear momentum squared 〈p02〉 as well as the electronic kinetic energy 12〈∑ipi2〉. The average excitation energy ΔE is also estimated from 〈q2〉(a,b) and 〈t2〉(a,b)." @default.
- W1979544605 created "2016-06-24" @default.
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- W1979544605 creator A5088734046 @default.
- W1979544605 date "2001-09-01" @default.
- W1979544605 modified "2023-09-26" @default.
- W1979544605 title "Physical significance of second electron-pair moments in position and momentum spaces" @default.
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- W1979544605 doi "https://doi.org/10.1063/1.1390511" @default.
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