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- W1979573733 abstract "N-Phosphinoylmethylamino acid derivatives 11–18 are obtained in high yield on N-bromomethylation of hexafluoroacetone protected amino acids 1–5 and subsequent Michaelis–Arbusov reaction. The carboxy activated species 11–18 react with a wide range of nucleophiles to give the unprotected N-phosphinoylmethylamino acids 19–22, amides 23–25, peptides 26–28, azapeptide 29 and the hydroxamic acid 30, respectively. The reaction sequence is suitable for generating libraries of N-phosphinoylmethylamino acid derivatives, which represent phosphonoamidate isosteres." @default.
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- W1979573733 date "1998-01-01" @default.
- W1979573733 modified "2023-09-23" @default.
- W1979573733 title "An efficient synthesis of N-phosphinoylmethylamino acids and some of their derivatives" @default.
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- W1979573733 doi "https://doi.org/10.1039/a801052h" @default.
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