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- W1979582132 abstract "Abstract Mn(II) complexes with 5-methylpyrazole (MP) ligands and selected anions are investigated using ESR and susceptibility measurements. Structural consequences of the combined action of MP ligands and anions from the magnetic properties of the unordered systems are deduced. For halogen anions essential local magnetic properties and very large zfs values (| D |=0.45; | E |=0.035 cm −1 ) with respect to Mn(II) are determined. In contrast, by using bifunctional anions, effective spin exchange processes govern the ESR spectra of polycrystalline solids and frozen aqueous solutions. In these, autonomous phases of solid complexes are established during the freezing process over a wide range of concentration of the constituents. These phases as well as the polycrystalline solids are characterized by single ESR lines of unusual width (Δ B PP =6 mT). The magnetic properties of the spin exchanging complexes can be understood in terms of an antiferromagnetic cluster model." @default.
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- W1979582132 date "1989-04-01" @default.
- W1979582132 modified "2023-09-26" @default.
- W1979582132 title "Magnetic interactions in Mn(II)—methylpyrazole complexes" @default.
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- W1979582132 doi "https://doi.org/10.1016/0022-2860(89)80177-2" @default.
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