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• W1979662497 abstract "A series of new L2PtMe2 and L2PtPh2 complexes have been prepared, where L2 = chelating diimine or NHC iminocarbene ligands with similar substituent patterns. These have been investigated by 1H- and 13C-NMR spectroscopy and single-crystal X-ray structure determinations to assess differences between the two ligand systems. All the three approaches underscore the strong trans influence of the N-heterocyclic carbene moiety relative to the imine group. This is supported by trends in J(195Pt–H) and J(195Pt–C) coupling constants in the hydrocarbyl NMR resonances as well as in differences in Pt–ligand bond distances trans to the imine and carbene moieties. This is paralleled by a clear trans effect of the carbene ligand in protonolysis; treatment of the Pt(II) dimethyl or diphenyl iminocarbene complexes with acid causes the elimination of methane and benzene, respectively, with selective loss of the methyl or phenyl groups from the trans position relative to the carbene part of the chelating ligand." @default.
• W1979662497 created "2016-06-24" @default.
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• W1979662497 date "2010-07-20" @default.
• W1979662497 modified "2023-10-18" @default.
• W1979662497 title "Pt(II) complexes with diimine and chelating 5-ring iminocarbene ligands: synthesis, characterization, and structural and spectroscopic trends" @default.
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• W1979662497 doi "https://doi.org/10.1080/00958972.2010.505648" @default.
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