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- W1979675062 abstract "Photoelectron spectroscopy (XPS and UPS) was used to study the deposition of metal layers (Ag, Cu, and Au) onto pentacene films. Very low work functions were measured (ΦAg = 3.91 eV, ΦCu = 3.93 eV, and ΦAu = 4.3 eV) for all of the metals, in agreement with results from the literature. The intensities of the C 1s core-level signals from pentacene that were monitored during stepwise metal deposition leveled off at a value of about 30% of a thick pentacene film. This C 1s intensity is comparable to that of one monolayer of pentacene deposited onto the respective metal. The valence band spectra of metals deposited onto pentacene and spectra collected for pentacene deposited onto bare metal surfaces are very similar. These findings lead to the conclusion that approximately one monolayer of pentacene is always present on top of the freshly deposited metal film, which explains the very low work function of the metals when they are deposited onto organic films. We expect similar behavior with other nonreactive metals deposited onto stable organic layers." @default.
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- W1979675062 date "2007-10-13" @default.
- W1979675062 modified "2023-10-17" @default.
- W1979675062 title "Ubiquitous Pentacene Monolayer on Metals Deposited onto Pentacene Films" @default.
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- W1979675062 doi "https://doi.org/10.1021/la701859g" @default.
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