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• W1979685489 abstract "As a model compound of flavin-adenine dinucleotide, the crystal and molecular structure of a 1:1 molecular complex of adenine and riboflavin has been determined by an X-ray diffraction method. There are two independent 1:1 complexes in an asymmetric unit, and, in both complexes, adenine and riboflavin molecules were connected by similar reversed Hoogsteen-type hydrogen bonds. In addition, nearly coplanar adenine and isoalloxazine rings interact with each other to form an infinite alternate stacking. Riboflavin molecules were found to have two rotational isomers about the glycosyl bond and the orientations of carbon atoms in the ribityl chain are nonplanar to avoid intramolecular nonbonding short contacts. These two conformations are significant to considerations of plausible flavin-adenine dinucleotide models consistent with the results of nuclear magnetic resonance studies." @default.
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• W1979685489 date "1977-06-01" @default.
• W1979685489 modified "2023-10-18" @default.
• W1979685489 title "Crystal and molecular structure of a 1:1 molecular complex of adenine and riboflavin" @default.
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• W1979685489 doi "https://doi.org/10.1016/0003-9861(77)90241-7" @default.
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