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- W1979714294 abstract "The synthesis, acid–base behaviour and Cu2+ and Zn2+ co-ordination studies in aqueous solution of the new open-chain compounds, N-(3-aminopropyl)-N′-3-(2,2′-bithien-5-ylmethyl)aminopropylethane-1,2-diamine (L1) and N-(2-aminoethyl)-N″-2-(2,2′-bithien-5-ylmethyl)aminoethyl diethylen-1,4,7-triamine (L2), resulting from the linkage of polyamine chains with a bithiophene unit have been explored by means of pH titrations and NMR techniques. The electrochemical behaviours of L1 and of the system Cu2+–L1 have been studied by linear scan, cyclic, and differential pulse voltammetry in the pH range 3–11. The results denote that the electrochemical pattern of L1 differs from that previously described for macrocyclic polyazathiophenophane receptors, for which relatively stable Cu(I) intermediates were detected." @default.
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- W1979714294 date "2002-06-01" @default.
- W1979714294 modified "2023-10-18" @default.
- W1979714294 title "Synthesis, acid–base behaviour, co-ordination and electrochemistry studies on new open-chain bithiophene receptors" @default.
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- W1979714294 doi "https://doi.org/10.1016/s0277-5387(02)00974-9" @default.
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