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• W1979722003 abstract "We have gained some insight into the role of conformational effects on the regioselectivity of the macrocyclic intramolecular nitrile oxide cycloaddition observed in our (+)-brefeldin A synthesis. During the course of this regiochemical study, we have developed two novel stereoselective and regioselective schemes for total synthesis of (+)-brefeldin A (i.e. intramolecular nitrile oxide cycloaddition-isomerization and intermolecular nitrile oxide cycloaddition-ring closing metathesis strategies)." @default.
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• W1979722003 date "2002-01-15" @default.
• W1979722003 modified "2023-10-17" @default.
• W1979722003 title "Role of Conformational Effects on the Regioselectivity of Macrocyclic INOC Reactions: Two New Asymmetric Total Syntheses of (+)-Brefeldin A^,¹" @default.
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• W1979722003 doi "https://doi.org/10.1021/jo010744a" @default.
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