FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1979757536> ?p ?o ?g. }

• W1979757536 endingPage "7426" @default.
• W1979757536 startingPage "7421" @default.
• W1979757536 abstract "We report the tuning of the redox properties of iron and iron oxide nanoparticles by encapsulation within carbon nanotubes (CNTs) with varying inner diameters. Raman spectroscopy was employed to investigate the interaction of the encapsulated nanoparticles with the CNTs. A red shift of the Fe−O mode is observed in the nanoparticles deposited on the outer CNT surfaces with respect to bulk Fe2O3. However, this mode is found to be stepwise blue-shifted with decreasing inner diameter in the CNT-encapsulated Fe2O3 nanoparticles, suggesting an enhanced interaction of Fe2O3 with the inner CNT surface as its curvature increases. The autoreduction of the encapsulated Fe2O3 is significantly facilitated inside CNTs with respect to the outside nanoparticles. Interestingly, it becomes more facile with decreasing CNT channel diameter as evidenced by temperature programmed reaction, in situ XRD, and Raman spectroscopy. The oxidation of encapsulated metallic Fe nanoparticles on the other hand is retarded in comparison to that of the outside Fe particles as shown by in situ XRD and gravimetrical measurements with an online microbalance. We attribute this tunable redox behavior of transition metal nanoparticles inside CNTs to a particular electronic interaction of the encapsulates with the interior CNT surface, which stabilizes the metallic state of Fe." @default.
• W1979757536 created "2016-06-24" @default.
• W1979757536 creator A5017541508 @default.
• W1979757536 creator A5045204358 @default.
• W1979757536 creator A5075748581 @default.
• W1979757536 date "2007-05-18" @default.
• W1979757536 modified "2023-10-02" @default.
• W1979757536 title "Tuning of Redox Properties of Iron and Iron Oxides via Encapsulation within Carbon Nanotubes" @default.
• W1979757536 cites W120269517 @default.
• W1979757536 cites W1975853346 @default.
• W1979757536 cites W1983220396 @default.
• W1979757536 cites W1987773763 @default.
• W1979757536 cites W1989704479 @default.
• W1979757536 cites W1991164957 @default.
• W1979757536 cites W1996236533 @default.
• W1979757536 cites W2000673688 @default.
• W1979757536 cites W2011152019 @default.
• W1979757536 cites W2015856769 @default.
• W1979757536 cites W2016980595 @default.
• W1979757536 cites W2024538550 @default.
• W1979757536 cites W2025931031 @default.
• W1979757536 cites W2026469372 @default.
• W1979757536 cites W2027500981 @default.
• W1979757536 cites W2032027336 @default.
• W1979757536 cites W2032129966 @default.
• W1979757536 cites W2045903743 @default.
• W1979757536 cites W2051940566 @default.
• W1979757536 cites W2054551180 @default.
• W1979757536 cites W2061204187 @default.
• W1979757536 cites W2073252674 @default.
• W1979757536 cites W2075058901 @default.
• W1979757536 cites W2079143372 @default.
• W1979757536 cites W2080492596 @default.
• W1979757536 cites W2083162390 @default.
• W1979757536 cites W2090176487 @default.
• W1979757536 cites W2101736818 @default.
• W1979757536 cites W2119037655 @default.
• W1979757536 cites W2143574394 @default.
• W1979757536 cites W2145566519 @default.
• W1979757536 cites W2145691476 @default.
• W1979757536 cites W2157792021 @default.
• W1979757536 cites W34580316 @default.
• W1979757536 cites W74602257 @default.
• W1979757536 doi "https://doi.org/10.1021/ja0713072" @default.
• W1979757536 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17508751" @default.
• W1979757536 hasPublicationYear "2007" @default.
• W1979757536 type Work @default.
• W1979757536 sameAs 1979757536 @default.
• W1979757536 citedByCount "311" @default.
• W1979757536 countsByYear W19797575362012 @default.
• W1979757536 countsByYear W19797575362013 @default.
• W1979757536 countsByYear W19797575362014 @default.
• W1979757536 countsByYear W19797575362015 @default.
• W1979757536 countsByYear W19797575362016 @default.
• W1979757536 countsByYear W19797575362017 @default.
• W1979757536 countsByYear W19797575362018 @default.
• W1979757536 countsByYear W19797575362019 @default.
• W1979757536 countsByYear W19797575362020 @default.
• W1979757536 countsByYear W19797575362021 @default.
• W1979757536 countsByYear W19797575362022 @default.
• W1979757536 countsByYear W19797575362023 @default.
• W1979757536 crossrefType "journal-article" @default.
• W1979757536 hasAuthorship W1979757536A5017541508 @default.
• W1979757536 hasAuthorship W1979757536A5045204358 @default.
• W1979757536 hasAuthorship W1979757536A5075748581 @default.
• W1979757536 hasConcept C106773901 @default.
• W1979757536 hasConcept C120665830 @default.
• W1979757536 hasConcept C121332964 @default.
• W1979757536 hasConcept C127413603 @default.
• W1979757536 hasConcept C155672457 @default.
• W1979757536 hasConcept C161790260 @default.
• W1979757536 hasConcept C171250308 @default.
• W1979757536 hasConcept C178790620 @default.
• W1979757536 hasConcept C179104552 @default.
• W1979757536 hasConcept C185592680 @default.
• W1979757536 hasConcept C192562407 @default.
• W1979757536 hasConcept C2777697756 @default.
• W1979757536 hasConcept C2778889443 @default.
• W1979757536 hasConcept C40003534 @default.
• W1979757536 hasConcept C42360764 @default.
• W1979757536 hasConcept C513720949 @default.
• W1979757536 hasConcept C544153396 @default.
• W1979757536 hasConcept C55904794 @default.
• W1979757536 hasConceptScore W1979757536C106773901 @default.
• W1979757536 hasConceptScore W1979757536C120665830 @default.
• W1979757536 hasConceptScore W1979757536C121332964 @default.
• W1979757536 hasConceptScore W1979757536C127413603 @default.
• W1979757536 hasConceptScore W1979757536C155672457 @default.
• W1979757536 hasConceptScore W1979757536C161790260 @default.
• W1979757536 hasConceptScore W1979757536C171250308 @default.
• W1979757536 hasConceptScore W1979757536C178790620 @default.
• W1979757536 hasConceptScore W1979757536C179104552 @default.
• W1979757536 hasConceptScore W1979757536C185592680 @default.
• W1979757536 hasConceptScore W1979757536C192562407 @default.
• W1979757536 hasConceptScore W1979757536C2777697756 @default.
• W1979757536 hasConceptScore W1979757536C2778889443 @default.
• W1979757536 hasConceptScore W1979757536C40003534 @default.
• W1979757536 hasConceptScore W1979757536C42360764 @default.

• next