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- W1979761714 abstract "Total synthesis of enantiopure (R)-(−)-massoialactone was achieved. The key step includes the asymmetric hydrogenation of an achiral β-keto ester using a ruthenium-SYNPHOS® catalyst to set the hydroxyl function in a stereocontrolled manner with excellent enantioselectivity (>99% ee). Ring closing metathesis (RCM) in the presence of Grubbs’ catalyst allows the final construction of the six-membered lactone." @default.
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- W1979761714 date "2006-12-01" @default.
- W1979761714 modified "2023-10-18" @default.
- W1979761714 title "Synthesis of enantiopure (R)-(−)-massoialactone through ruthenium-SYNPHOS® asymmetric hydrogenation" @default.
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- W1979761714 doi "https://doi.org/10.1016/j.tetasy.2006.11.048" @default.
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