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- W1979771840 abstract "Nanostructured ethylenediamine functionalized polysilsesquioxane (EDA-PSQ) macromolecules have been successfully synthesized by a facile one-pot miniemulsion route using organosilane monomer N-(3-Trimethoxysilylethyl)ethylenediamine (TMSEEDA) as the sole precursor for the first time. The particles exhibit spherical morphology with an average diameter of around 110 nm. Under UV light excitation, the nanostructured EDA-PSQs show unexpected intense blue emission bands consisting of peaks at 407, 437 and 478 nm, affording environmental friendly blue-light-emitting nanocomposites and promising for optoelectronic and biological applications. Further, after heating treatment at 500 °C, the blue emission bands disappear along with the emergence of a new and faint red emission band at 615 nm. The possible mechanisms for the blue emissions are discussed." @default.
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- W1979771840 date "2012-12-01" @default.
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- W1979771840 title "Facile one-pot synthesis of multifunctional and blue-light-emitting nanostructured polysilsesquioxane macromolecules via a miniemulsion process" @default.
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- W1979771840 doi "https://doi.org/10.1016/j.matlet.2012.08.086" @default.
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