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- W1979804898 abstract "In experiments modeling the reactions of the reductive acetyl-coenzyme A pathway at hydrothermal temperatures, it was found that an aqueous slurry of coprecipitated NiS and FeS converted CO and CH3SH into the activated thioester CH3-CO-SCH3, which hydrolyzed to acetic acid. In the presence of aniline, acetanilide was formed. When NiS-FeS was modified with catalytic amounts of selenium, acetic acid and CH3SH were formed from CO and H2S alone. The reaction can be considered as the primordial initiation reaction for a chemoautotrophic origin of life." @default.
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- W1979804898 date "1997-04-11" @default.
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- W1979804898 title "Activated Acetic Acid by Carbon Fixation on (Fe,Ni)S Under Primordial Conditions" @default.
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- W1979804898 doi "https://doi.org/10.1126/science.276.5310.245" @default.
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