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- W1979807029 abstract "The first insertion of a silylene into a MN bond was observed in the presented transformations of the thermally stable silylene 1, Np = neopentyl, with metal(II) bis(silyl)amides. Bis(silyl)metal(II) compounds 2 and 3 were obtained for M = Sn and Pb, respectively, whereas a colorless azadisilager-mole was formed for M Ge. Noteworthy is the very long SnSi bond of 2.712(2) Å in 2." @default.
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- W1979807029 date "1997-12-01" @default.
- W1979807029 modified "2023-10-17" @default.
- W1979807029 title "New Reactions of a Silylene: Insertion into MN Bonds of M[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>2</sub> (M Ge, Sn, or Pb)" @default.
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- W1979807029 doi "https://doi.org/10.1002/anie.199725141" @default.
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