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- W1979814912 abstract "Abstract— The 3-tyrosinyl free radicals (3-Tyr) and iodine atom are formed by flash photolysis of 3-iodotyrosine (3-Tyr-I) in aqueous solutions at pH 5. The presence of iodine atoms in the medium is characterized by the absorption spectrum and the decay kinetics of I formed when KI is added to the system. In the absence of radical scavengers, the 3-Tyr adds to or reacts with the parent molecule to produce a transient species, probably a radical dimer, which has an absorption maximum at 405 nm. The decay of this transient follows second order kinetics whose rate constant increases with decreasing 3-iodotyrosine concentration. Measurements of the dependence of the transient yield on the concentration of added ethanol indicate that the 3-Tyr radical reacts with ethanol by hydrogen abstraction. The rate constants of reaction of the 3-Tyr radical with 3-iodotyrosine and ethanol are deduced from results." @default.
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- W1979814912 date "1978-08-01" @default.
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- W1979814912 title "FLASH PHOTOLYSIS OF 3-IODOTYROSINE IN AQUEOUS SOLUTION AT pH 5" @default.
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- W1979814912 doi "https://doi.org/10.1111/j.1751-1097.1978.tb07693.x" @default.
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