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- W1979825926 abstract "The BH 3 -protected phosphinoindenyl ligand indenyl(CH 2 ) 2 PPh 2 ·BH 3 was used in the preparation of (η 5/3 :η 0 -indenyl(CH 2 ) 2 PPh 2 ·BH 3 )Ni(PPh 3 )Cl, which has been characterized by NMR spectroscopy and X-ray diffraction studies. On the other hand, all attempts at preparing the closely related complex (η 5/3 :η 1 -indenyl(CH 2 ) 2 PPh 2 )NiCl, in which the tethered phosphine moiety is coordinated to the Ni centre, were unsuccessful. One of these unsuccessful attempts yielded instead the novel indenyl-PCP pincer complex {κ P ,κ C ,κ P -1,3-(CH 2 CH 2 PPh 2 ) 2 -2-indenyl}NiCl, which has been characterized by X-ray diffraction studies.Key words: indenyl complexes, tethered phosphines, PCP pincer complexes." @default.
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- W1979825926 date "2005-06-01" @default.
- W1979825926 modified "2023-10-06" @default.
- W1979825926 title "Phosphino-indenyl complexes of nickel(II)" @default.
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- W1979825926 doi "https://doi.org/10.1139/v05-079" @default.
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