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- W1979874798 abstract "Illinois No. 6 coal has been swollen in pyridine—chlorobenzene mixture and the composition of the solvent inside the coal measured. Pyridine disrupts the non-covalent crosslinks in coal, so the addition of very small amounts of pyridine leads to an enormous increase in the uptake of chlorobenzene by the coal. The sites which interact specifically with pyridine can be titrated by measuring the composition of the solvent absorbed by the coal. Bruceton coal has been swollen by mixtures of alcohols with N,N-dimethylaniline. About the same amount of methanol, ethanol, and propanol are absorbed by pyridine-extracted coal, suggesting the existence of specific sites for alcohol binding. Significantly less t-butanol is bound, presumably due to steric effects. The swelling behaviour of extracted and unextracted coals are quite different, since pyridine extraction destroys many non-covalent crosslinks. The interactions of these solvents with coal are very sensitive to the ability of the solvents to interact specifically with the coal and, in doing so, to destroy non-covalent crosslinks." @default.
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- W1979874798 date "1984-11-01" @default.
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- W1979874798 title "Coal swelling in binary solvent mixtures: Pyridine—chlorobenzene and N,N-dimethylaniline—alcohol" @default.
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- W1979874798 doi "https://doi.org/10.1016/0016-2361(84)90222-9" @default.
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