FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1979911697> ?p ?o ?g. }

• W1979911697 endingPage "219" @default.
• W1979911697 startingPage "212" @default.
• W1979911697 abstract "A combination of in situ Raman spectroelectrochemistry and cyclic voltammetric (CV) stripping methods is used to study the adsorption/desorption of benzenethiol (BT) at platinum (Pt) alloy electrodes. The data from both methods confirm that alloying Pt with Fe group metals enhances the sulfur tolerance of the alloy over Pt. The Raman signal of BT adsorbed at electrodeposited films of Pt3Co and Pt4Ni diminishes to a greater extent after only one oxidation/reduction cycle than that observed for BT adsorbed at pure Pt films. Oxidatively desorbed BT readsorbs at Pt3Co at a potential that is ∼50 mV lower than that at which it readsorbs at either Pt or Pt4Ni films, further demonstrating its enhanced sulfur tolerance. Sulfate bands are absent from the spectra of all films, indicating that the metal–S bonds that form upon adsorption are broken during oxidative removal of BT rather than cleavage of C–S bonds in the BT adsorbate. The CV stripping data confirm that BT is more readily electrochemically stripped from the alloy films than from pure Pt films. The combination of Raman spectroelectrochemistry and CV stripping enables more comprehensive characterization of sulfur-tolerant electrocatalyst surfaces in situ, under electrochemical conditions." @default.
• W1979911697 created "2016-06-24" @default.
• W1979911697 creator A5044882389 @default.
• W1979911697 creator A5062951672 @default.
• W1979911697 date "2012-08-01" @default.
• W1979911697 modified "2023-10-16" @default.
• W1979911697 title "A Raman spectroelectrochemical study of potential-controlled benzenethiol desorption from Pt–Fe group alloy films" @default.
• W1979911697 cites W1972578480 @default.
• W1979911697 cites W1977998726 @default.
• W1979911697 cites W1978017388 @default.
• W1979911697 cites W1978333079 @default.
• W1979911697 cites W1982584850 @default.
• W1979911697 cites W1988726814 @default.
• W1979911697 cites W1992149671 @default.
• W1979911697 cites W1994033390 @default.
• W1979911697 cites W1995307645 @default.
• W1979911697 cites W1995877716 @default.
• W1979911697 cites W2002389930 @default.
• W1979911697 cites W2002922257 @default.
• W1979911697 cites W2003661696 @default.
• W1979911697 cites W2008457049 @default.
• W1979911697 cites W2010655698 @default.
• W1979911697 cites W2013792663 @default.
• W1979911697 cites W2015716054 @default.
• W1979911697 cites W2016384041 @default.
• W1979911697 cites W2023812902 @default.
• W1979911697 cites W2029333493 @default.
• W1979911697 cites W2037002914 @default.
• W1979911697 cites W2039453064 @default.
• W1979911697 cites W2045008379 @default.
• W1979911697 cites W2045641934 @default.
• W1979911697 cites W2050228409 @default.
• W1979911697 cites W2059538479 @default.
• W1979911697 cites W2083838435 @default.
• W1979911697 cites W2087543718 @default.
• W1979911697 cites W2100743842 @default.
• W1979911697 cites W2100758525 @default.
• W1979911697 cites W2112959450 @default.
• W1979911697 cites W2115729799 @default.
• W1979911697 cites W2130949639 @default.
• W1979911697 cites W2314518066 @default.
• W1979911697 doi "https://doi.org/10.1016/j.jpowsour.2012.04.010" @default.
• W1979911697 hasPublicationYear "2012" @default.
• W1979911697 type Work @default.
• W1979911697 sameAs 1979911697 @default.
• W1979911697 citedByCount "3" @default.
• W1979911697 countsByYear W19799116972016 @default.
• W1979911697 countsByYear W19799116972018 @default.
• W1979911697 countsByYear W19799116972022 @default.
• W1979911697 crossrefType "journal-article" @default.
• W1979911697 hasAuthorship W1979911697A5044882389 @default.
• W1979911697 hasAuthorship W1979911697A5062951672 @default.
• W1979911697 hasConcept C113196181 @default.
• W1979911697 hasConcept C120665830 @default.
• W1979911697 hasConcept C121332964 @default.
• W1979911697 hasConcept C147789679 @default.
• W1979911697 hasConcept C150394285 @default.
• W1979911697 hasConcept C161790260 @default.
• W1979911697 hasConcept C162711632 @default.
• W1979911697 hasConcept C17525397 @default.
• W1979911697 hasConcept C178790620 @default.
• W1979911697 hasConcept C179104552 @default.
• W1979911697 hasConcept C185592680 @default.
• W1979911697 hasConcept C191897082 @default.
• W1979911697 hasConcept C192562407 @default.
• W1979911697 hasConcept C2777869211 @default.
• W1979911697 hasConcept C2780026712 @default.
• W1979911697 hasConcept C33989665 @default.
• W1979911697 hasConcept C40003534 @default.
• W1979911697 hasConcept C518104683 @default.
• W1979911697 hasConcept C518881349 @default.
• W1979911697 hasConcept C52859227 @default.
• W1979911697 hasConcept C544153396 @default.
• W1979911697 hasConceptScore W1979911697C113196181 @default.
• W1979911697 hasConceptScore W1979911697C120665830 @default.
• W1979911697 hasConceptScore W1979911697C121332964 @default.
• W1979911697 hasConceptScore W1979911697C147789679 @default.
• W1979911697 hasConceptScore W1979911697C150394285 @default.
• W1979911697 hasConceptScore W1979911697C161790260 @default.
• W1979911697 hasConceptScore W1979911697C162711632 @default.
• W1979911697 hasConceptScore W1979911697C17525397 @default.
• W1979911697 hasConceptScore W1979911697C178790620 @default.
• W1979911697 hasConceptScore W1979911697C179104552 @default.
• W1979911697 hasConceptScore W1979911697C185592680 @default.
• W1979911697 hasConceptScore W1979911697C191897082 @default.
• W1979911697 hasConceptScore W1979911697C192562407 @default.
• W1979911697 hasConceptScore W1979911697C2777869211 @default.
• W1979911697 hasConceptScore W1979911697C2780026712 @default.
• W1979911697 hasConceptScore W1979911697C33989665 @default.
• W1979911697 hasConceptScore W1979911697C40003534 @default.
• W1979911697 hasConceptScore W1979911697C518104683 @default.
• W1979911697 hasConceptScore W1979911697C518881349 @default.
• W1979911697 hasConceptScore W1979911697C52859227 @default.
• W1979911697 hasConceptScore W1979911697C544153396 @default.
• W1979911697 hasLocation W19799116971 @default.
• W1979911697 hasOpenAccess W1979911697 @default.
• W1979911697 hasPrimaryLocation W19799116971 @default.
• W1979911697 hasRelatedWork W2010872403 @default.

• next