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- W1979929950 abstract "The effects of density on the Fermi resonance interaction in CO2 up to 534 amagat density was investigated. The Raman intensity of the polarized, anisotropic, and isotropic components of the 2ν2 and ν1 bands was determined as a function of the fluid density. By using the theory of Fermi resonance coupling the ratio of the unperturbed Raman polarizability matrix elements of the 2ν2 and ν1 bands was determined as a function of the fluid density. Changes in the vibrational anharmonicity, and an increasing repulsion of the vibration levels were found to decrease the effectiveness of the resonance interaction as the fluid density was increased, therefore altering the Raman intensity and frequency with changing density." @default.
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- W1979929950 date "1973-11-01" @default.
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- W1979929950 title "Raman studies of the effect of density of the fermi resonance in CO2" @default.
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- W1979929950 doi "https://doi.org/10.1016/0009-2614(73)80261-1" @default.
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