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- W1979935316 abstract "The linear driving force (LDF) model is applied to predict the service life of activated carbon cartridges. It is compared with the currently used Wheeler-Jonas equation, which results from a model of chemical reaction kinetics. The LDF model is based on a mass transfer model of adsorbate into the particle. The two models are studied in constant-pattern conditions. The properties of the two models are first clarified and then compared. It is shown that the Wheeler-Jonas equation leads to symmetrical breakthrough curves, whereas the constant-pattern LDF equation results in asymmetrical curves. Thus, the curvature of the isotherm has no influence on the shape of the Wheeler-Jonas curve. For the LDF breakthrough curve, it is shown that the asymmetry increases with the curvature of the isotherm. Wheeler-Jonas can be used with a Dubinin-Raduskevitch isotherm, whereas the LDF model analytical solution is valid for a Langmuir isotherm only. The LDF model can be used with the DR isotherm, but a numerical solution is required. At very low concentrations where the isotherm is linear, the constant pattern no longer exists and both models fail. The Dubinin-Raduskevitch isotherm must be fitted with a Langmuir isotherm to use the analytical solution of the LDF model." @default.
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- W1979935316 date "2011-04-19" @default.
- W1979935316 modified "2023-09-25" @default.
- W1979935316 title "A Comparison of the Wheeler-Jonas Model and the Linear Driving Force at Constant-Pattern Model for the Prediction of the Service Time of Activated Carbon Cartridges" @default.
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- W1979935316 doi "https://doi.org/10.1080/15459624.2011.567131" @default.
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