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• W1979941872 abstract "Boron carbides $({mathrm{B}}_{x}{mathrm{C}}_{1ensuremath{-}x})$ in thin film form have been synthesized in a high vacuum by coevaporation of B and C atoms from independent sources, allowing a study of the whole composition range from pure B films to pure C films. The relationship between the impinging $mathrm{B}∕mathrm{C}$ atomic fluxes and the film composition has been studied, providing information on the chemical reactivity between the B and C vapors. The composition was determined with x-ray emission energy dispersion spectroscopy and x-ray absorption near edge spectroscopy (XANES). Finally, the bonding structure of the films has been determined by XANES, showing a change from structures based on ${mathrm{B}}_{12}$-icosahedral units for the B-rich samples to hexagonal-like structures for the C-rich samples. The study shows that the structural transition takes place for $xensuremath{sim}0.5$." @default.
• W1979941872 created "2016-06-24" @default.
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• W1979941872 date "2008-05-14" @default.
• W1979941872 modified "2023-09-26" @default.
• W1979941872 title "Boron carbides formed by coevaporation of B and C atoms: Vapor reactivity,<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mi mathvariant=normal>B</mml:mi><mml:mi>x</mml:mi></mml:msub><mml:msub><mml:mi mathvariant=normal>C</mml:mi><mml:mrow><mml:mn>1</mml:mn><mml:mo>−</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>composition, and bonding structure" @default.
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• W1979941872 doi "https://doi.org/10.1103/physrevb.77.174109" @default.
• W1979941872 hasPublicationYear "2008" @default.
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