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- W1979971872 abstract "Abstract Five nickel complexes, [Ni 2 (3,4,5‐tmb) 4 (4,4′‐bpy)] ( 1 ), [Ni 2 (2‐ntc) 4 (4,4′‐bpy)] ( 2 ), [Ni(9‐atc) 2 (4,4′‐bpy)] ( 3 ), [Ni(3,4,5‐tmb) 2 ( t ‐bpee)] ( 4 ), and [Ni 2 (2‐ntc) 4 ( t ‐bpee) 2 ] ( 5 ) (3,4,5‐tmb=3,4,5‐trimethoxybenzoate; 2‐ntc=2‐naphthalenecarboxylate; 9‐atc=9‐anthracenecarboxylate; 4,4′‐bpy=4,4′‐bipyridine; t ‐bpee= trans ‐1,2‐bis(4‐pyridyl)ethylene), are prepared. They are characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, and single‐crystal and powder X‐ray diffraction. 1 and 2 form linear chains of paddlewheel units joined by 4,4′‐bpy ligands; 3 and 4 display zigzag chains formed by cis ‐bis(chelate) Ni(O 2 CR) 2 units joined by 4,4′‐bpy and t ‐bpee, respectively; and the structure of 5 consists of double chains. The magnetic behavior of the compounds is also studied, and DFT calculations using the broken‐symmetry approximation are performed to gain a better understanding of the strong antiferromagnetism found in 1 ." @default.
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- W1979971872 date "2014-03-18" @default.
- W1979971872 modified "2023-10-18" @default.
- W1979971872 title "One-Dimensional [Ni(O<sub>2</sub>CR)<sub>2</sub>(NN)<sub><i>x</i></sub>] Polymers: Structural, Magnetic, and Density Functional Theory Studies" @default.
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- W1979971872 doi "https://doi.org/10.1002/cplu.201402005" @default.
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