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- W1979985152 abstract "The synthesis of a series of 3,6-disubstituted-1,2,4,5-tetrazines has been effected using an inverse electron demand [2 + 4] cycloaddition strategy. The crystal structures of 18 members of this series of diazafluoranthenes are reported. Stereochemical analysis shows that diazafluoranthenes, substituted across the bay region, are helically-twisted strained aromatic molecules. The dihedral angle between pyridazylvsnaphthyl rings ranges from 0.5° to 20.9°, and follows the degree of steric congestion in the bay region. The crystal structures are compared to computational structures determined using density functional theory, with the M06-2X/cc-pVDZ method." @default.
- W1979985152 created "2016-06-24" @default.
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- W1979985152 date "2009-01-01" @default.
- W1979985152 modified "2023-09-24" @default.
- W1979985152 title "Diels–Alder reactions of 3,6-disubstituted 1,2,4,5-tetrazines. Synthesis and X-ray crystal structures of diazafluoranthene derivatives" @default.
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- W1979985152 doi "https://doi.org/10.1039/b820551e" @default.
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