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- W1979990040 abstract "The host−guest complex [(C2B10H10Hg)4(NO3)2(H2O)][K(18-crown-6)]2(H2O)(CH3)2CO, 1, was formed from the reaction of 12-mercuracarborand-4 with 2 equiv of potassium nitrate/18-crown-6, while [(C2B10H10Hg)4(NO3)2][K(18-crown-6)]2, 2, was found to be the preferred product in the reaction of 12-mercuracarborand-4 with 3 equiv of potassium nitrate/18-crown-6. Both were isolated in almost quantitative yield from their respective reaction mixtures. The title complexes were characterized by multinuclear NMR spectroscopy, negative-ion FAB mass spectroscopy, and X-ray crystallography. In complex 2, the two bonded nitrate ions are each η3-coordinated with the oxygen atoms bonded face-on to the four Hg atoms of the planar host molecule." @default.
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- W1979990040 date "1999-05-01" @default.
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- W1979990040 title "Molecular Aggregates of Nitrate Ion with the Tetravalent Lewis Acid Host 12-Mercuracarborand-4: Novel Trihapto Coordination of NO3-" @default.
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- W1979990040 doi "https://doi.org/10.1021/ic9811244" @default.
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