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• W1980070612 abstract "Four π-extended, β,β′ aromatic ring fused porphyrins including mono- and opp-dibenzoporphyrins bearing two carboxyl groups at only one fused benzo group were synthesized. The optical results by UV–vis spectroscopy indicate that when compared with the absorption spectra of monobenzoporphyrins, greater light-harvesting capabilities can be realized for opp-dibenzoporphyrins with two benzo group at the opposite β,β′ positions of the porphyrin. The photovoltaic properties of these π-extended porphyrins were examined for the first time and the highest conversion efficiency of 1.62% was realized for opp-dibenzoporphyrin 8a-sensitized solar cell, which is ∼60% higher than that of monobenzoporphyrin 4a based solar cell indicating the effect of an extra aromatic π conjugation on the light-harvesting capabilities of π-extended porphyrins. Subsequent DFT calculation results supported our results obtained in the optical and photovoltaic studies." @default.
• W1980070612 created "2016-06-24" @default.
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• W1980070612 date "2013-12-01" @default.
• W1980070612 modified "2023-09-23" @default.
• W1980070612 title "Synthesis of β,β′-edge fused, π-extended porphyrins and their applications in the dye-sensitized solar cells" @default.
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• W1980070612 doi "https://doi.org/10.1016/j.tetlet.2013.10.132" @default.
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