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• W1980073044 abstract "A general criterion is formulated for molecular recognition. The criterion for recognition is the inequality of the distance matrices of complexes of different compounds with a resolving agent under ambient experimental conditions. It is shown how this criterion provides for an objective, well-defined, and simple explanation for recognition of chiral compounds. This approach may be used to explain models (e.g., three-point of attachment) and relationships for chiral recognition. It is also shown how one-, two-, or three-point mechanisms are equivalent in this formalism and could result in chiral recognition. Examples are used to illustrate how the so called one- or two-point mechanisms may be operative in many experimental findings. Symmetry requirements of resolving agents may also be derived from considerations of distance matrices. Finally, the reciprocal relationship of chiral resolving agents is easily derived from the present method of analysis." @default.
• W1980073044 created "2016-06-24" @default.
• W1980073044 creator A5055148490 @default.
• W1980073044 date "1989-01-01" @default.
• W1980073044 modified "2023-10-12" @default.
• W1980073044 title "A general criterion for molecular recognition: Implications for chiral interactions" @default.
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• W1980073044 doi "https://doi.org/10.1002/chir.530010113" @default.
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