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• W1980097013 startingPage "3328" @default.
• W1980097013 abstract "When two atoms are in proximity, their resonance lines are broadened because of the formation of molecular potentials, between which photon transitions can occur. The level of experimental refinement in measuring excimer and collisional far-wing spectra calls for interpretive theoretical methods that accurately treat the observed structure in line shapes. Of particular interest are satellites and undulations, for they can give much information on intermolecular potentials. We derive an expression for $T$-matrix elements, based on JWKB wave functions and stationary-phase techniques, that is universally applicable to situations with one, two, or more Condon points. Each transition point is treated individually, with effects of potential shape, wave-function phases, and interference separately highlighted. The expression is tested against quantum-mechanical line shapes of the red and blue wings of the Rb $D$ lines broadened by Xe perturbers. Agreement is quite good for both the red-wing undulations and the blue-wing satellite-supernumerary structure." @default.
• W1980097013 created "2016-06-24" @default.
• W1980097013 creator A5036178188 @default.
• W1980097013 creator A5073979269 @default.
• W1980097013 date "1983-12-01" @default.
• W1980097013 modified "2023-09-25" @default.
• W1980097013 title "Universal stationary-phase treatment of far-wing and excimer spectral line shapes" @default.
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• W1980097013 doi "https://doi.org/10.1103/physreva.28.3328" @default.
• W1980097013 hasPublicationYear "1983" @default.
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