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• W1980105377 abstract "A new chemical strategy for the preparation of a homogeneous SiTiZr sol was developed. The procedure is based on strategies developed for the SiTi and SiZr. Sols were characterized by Fourier transform infrared spectroscopy (FTIR). Assignments of the simultaneous formation of the SiOTi and SiOZr bonds were made. The xerogels and oxides were also analyzed by 29Si CP MAS NMR, X-ray diffraction (XRD), transmission electron microscopy (TEM) and electron paramagnetic resonance. Zr inhibits condensation of the siloxane species in the xerogels. All the solid samples, including those calcined at 900°C were amorphous. EPR results indicate that the Ti(III) symmetry is octahedrally distorted." @default.
• W1980105377 created "2016-06-24" @default.
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• W1980105377 date "1997-08-01" @default.
• W1980105377 modified "2023-09-27" @default.
• W1980105377 title "Homogeneous SiTi and SiTiZr polymeric systems obtained from monomeric precursors" @default.
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• W1980105377 doi "https://doi.org/10.1016/s0022-3093(97)00111-7" @default.
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