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• W1980124209 abstract "The electron paramagnetic resonance of copper(II) doped in a single crystal of L-histidine· HCl monohydrate indicates that the Cu2+ ion is incorporated in a different environment from that in the ordinary bis(L-histidinyl)copper(II) complex. The coefficients of the ground state Kramer's doublet were determined from the observed g tensor (gz = 2.013, gx = 2.262, gv = 2.153) in such a way that the hyperfine parameters calculated from the coefficients closely reproduce the observed values. The results show that the half-filled d orbital is of the dz2 type, suggesting an axially compressed structure. The polarized single crystal absorption spectra taken in the three perpendicular crystal faces exhibit three d-d transitions at 14 000, 12 800 and 11 100 cm−1, which are polarized mostly along the c, b, and a crystal axes, respectively. By combining the optical and the paramagnetic resonance results, the one-electron orbital sequence was found to be dz2&gt;dx2-y2&gt;dyz&gt;dxy&gt;dxz. For a possible site of copper incorporation an interstitial position was chosen which has approximately D2 symmetry." @default.
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• W1980124209 date "1972-05-01" @default.
• W1980124209 modified "2023-09-26" @default.
• W1980124209 title "Electron Paramagnetic Resonance and Polarized Absorption Spectra of Cu(II)‐Doped Single Crystal of L‐Histidine Hydrochloride Monohydrate" @default.
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• W1980124209 doi "https://doi.org/10.1063/1.1677890" @default.
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