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- W1980147146 abstract "A series of sulfonated polyimides (SPI) ionomers were synthesized from a new flexible dianhydride of 4,4′-ketone dinaphthalene 1,1′,8,8′-tetracarboxylic dianhydride (KDNTDA), a sulfonated diamine of 4,4′-bis(4-aminophenoxy)biphenyl-3,3′-disulfonic acid and nonsulfonated diamines including dimethylsiloxane oligomer-based diamine. KDNTDA-based SPIs displayed good solubility in common aprotic solvents, which would provide an advantage of easy processing, being different from SPIs derived from 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTDA). They showed reasonably high proton conductivities and anisotropic membrane swelling with 2–3 times larger swelling in thickness than in plane. KDNTDA-based SPIs displayed slightly lower water stability than that of NTDA-based ones. On the other hand, the branched/crosslinked KDNTDA-based SPI membrane displayed higher water stability and kept high mechanical property and proton conductivity even after the aging in water at 130 °C for 300 h." @default.
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- W1980147146 date "2008-04-01" @default.
- W1980147146 modified "2023-09-28" @default.
- W1980147146 title "Synthesis and properties of novel sulfonated polyimides derived from naphthalenic dianhydride for fuel cell application" @default.
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- W1980147146 doi "https://doi.org/10.1016/j.memsci.2007.12.069" @default.
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