Matches in SemOpenAlex for { <https://semopenalex.org/work/W1980149069> ?p ?o ?g. }
Showing items 1 to 66 of
66
with 100 items per page.
- W1980149069 endingPage "1711" @default.
- W1980149069 startingPage "1703" @default.
- W1980149069 abstract "Sulphurous negative ions S • SH • SO • SO 2 /S 2 • SO 3 • HSO 3 • SO 4 • and HSO 4 were observed when 0.2% of carbonyl sulphide (OCS) was added to a conical, laminar, premixed. fuel-rich (equivalence ratio [Formula: see text]) CH 4 –O 2 flame burning at atmospheric pressure. Profiles were obtained of ion concentration vs. distance along the flame axis by sampling the flame through a pinhole into a quadrupole mass spectrometer. Some of the ion signals observed in the flame reaction zone are very large, particularly that for HSO 4 . None of the sulphurous ions detected contain carbon. Of those listed above, only S − ,•SH, • SO • and SO 2 persist downstream through the burnt gas. The sulphurous ions are formed by chemical ionization processes of neutral sulphurous intermediates reacting with the naturally-occurring ions present in any hydrocarbon flame. The ion chemistry is discussed, as is the underlying neutral chemistry of sulphur relevant to the flame environment. The ion profiles show the rapidity with which OCS is oxidized through SH and SO to SO 2 even within the reaction zone of this fuel-rich flame. No evidence was obtained for the presence of sulphuric or sulphurous acids, and the presence of S 2 : was not confirmed." @default.
- W1980149069 created "2016-06-24" @default.
- W1980149069 creator A5031903672 @default.
- W1980149069 creator A5043332857 @default.
- W1980149069 creator A5057447148 @default.
- W1980149069 date "1983-08-01" @default.
- W1980149069 modified "2023-10-10" @default.
- W1980149069 title "Sulphurous negative ions in a fuel-rich, CH4–O2 flame with OCS additive" @default.
- W1980149069 doi "https://doi.org/10.1139/v83-291" @default.
- W1980149069 hasPublicationYear "1983" @default.
- W1980149069 type Work @default.
- W1980149069 sameAs 1980149069 @default.
- W1980149069 citedByCount "10" @default.
- W1980149069 crossrefType "journal-article" @default.
- W1980149069 hasAuthorship W1980149069A5031903672 @default.
- W1980149069 hasAuthorship W1980149069A5043332857 @default.
- W1980149069 hasAuthorship W1980149069A5057447148 @default.
- W1980149069 hasConcept C103232671 @default.
- W1980149069 hasConcept C105923489 @default.
- W1980149069 hasConcept C113196181 @default.
- W1980149069 hasConcept C129474609 @default.
- W1980149069 hasConcept C145148216 @default.
- W1980149069 hasConcept C162356407 @default.
- W1980149069 hasConcept C178790620 @default.
- W1980149069 hasConcept C179104552 @default.
- W1980149069 hasConcept C185592680 @default.
- W1980149069 hasConcept C198291218 @default.
- W1980149069 hasConcept C2777207669 @default.
- W1980149069 hasConcept C43617362 @default.
- W1980149069 hasConcept C51884965 @default.
- W1980149069 hasConcept C83104080 @default.
- W1980149069 hasConceptScore W1980149069C103232671 @default.
- W1980149069 hasConceptScore W1980149069C105923489 @default.
- W1980149069 hasConceptScore W1980149069C113196181 @default.
- W1980149069 hasConceptScore W1980149069C129474609 @default.
- W1980149069 hasConceptScore W1980149069C145148216 @default.
- W1980149069 hasConceptScore W1980149069C162356407 @default.
- W1980149069 hasConceptScore W1980149069C178790620 @default.
- W1980149069 hasConceptScore W1980149069C179104552 @default.
- W1980149069 hasConceptScore W1980149069C185592680 @default.
- W1980149069 hasConceptScore W1980149069C198291218 @default.
- W1980149069 hasConceptScore W1980149069C2777207669 @default.
- W1980149069 hasConceptScore W1980149069C43617362 @default.
- W1980149069 hasConceptScore W1980149069C51884965 @default.
- W1980149069 hasConceptScore W1980149069C83104080 @default.
- W1980149069 hasIssue "8" @default.
- W1980149069 hasLocation W19801490691 @default.
- W1980149069 hasOpenAccess W1980149069 @default.
- W1980149069 hasPrimaryLocation W19801490691 @default.
- W1980149069 hasRelatedWork W1602738486 @default.
- W1980149069 hasRelatedWork W2021593687 @default.
- W1980149069 hasRelatedWork W2040842071 @default.
- W1980149069 hasRelatedWork W2079024976 @default.
- W1980149069 hasRelatedWork W2117673867 @default.
- W1980149069 hasRelatedWork W2120323094 @default.
- W1980149069 hasRelatedWork W2126107909 @default.
- W1980149069 hasRelatedWork W2328066903 @default.
- W1980149069 hasRelatedWork W4221046185 @default.
- W1980149069 hasRelatedWork W4256679449 @default.
- W1980149069 hasVolume "61" @default.
- W1980149069 isParatext "false" @default.
- W1980149069 isRetracted "false" @default.
- W1980149069 magId "1980149069" @default.
- W1980149069 workType "article" @default.