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• W1980197515 abstract "Kβ-to-Kα X-ray intensity ratios of Ti, V, Cr and Fe have been measured in pure metals and in the compounds of TiC, VC, CrB, CrB2 and FeB following excitation by 59.54 keV γ-rays from a 200 mCi 241Am point-source. Comparison of the measured Kβ-to-Kα X-ray intensity ratios with the multiconfiguration Dirac–Fock calculation indicates significant change in the 3d electron population of Ti in TiC and Cr in CrB and CrB2 from their pure metal values and almost no change for V in VC and Fe in FeB. In TiC we have found a transfer of 0.65±0.16 electrons from the 3d state of Ti whereas for CrB and CrB2 the 3d electron population of Cr increases by 0.60±0.30 and 0.75±0.30 electrons, respectively, over the pure metal value. Although our charge transfer result for TiC is closer to the prediction of the APW band structure calculations no firm conclusion can be made from our VC result. Our result for the relative Kβ-to-Kα ratio of VC with respect to pure V does not agree with the previously reported experimental result of Chang et al. (J. Phys. B: At. Mol. Opt. Phys. 27 (1994) 5251). Our results for CrB and CrB2 predict transfer of electrons from boron to 3d band of Cr in agreement with some of the earlier published results of magnetic and Hall effect measurements." @default.
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• W1980197515 date "1998-12-01" @default.
• W1980197515 modified "2023-10-16" @default.
• W1980197515 title "Influence of chemical effect on the Kβ-to-Kα X-ray intensity ratios of Ti, V, Cr and Fe in TiC, VC, CrB, CrB2 and FeB" @default.
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• W1980197515 doi "https://doi.org/10.1016/s0168-583x(98)00552-7" @default.
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