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- W1980239816 abstract "The copper-catalyzed azide-alkyne cycloaddition (CuAAC, “click chemistry”) was studied employing copper-in-charcoal (Cu/C) and a variety of copper metal sources as “heterogeneous” catalysts. The type and pretreatment conditions of the different copper sources on the CuAAC were investigated. In addition, the effect of copper leaching from the catalyst over time and in dependence on the reaction mixture composition was studied by ICP-MS analysis in the continuous flow mode. These investigations confirm a “homogeneous” mechanism and suggest surface layer copper(I) oxide as the catalytically active species in CuAAC chemistry involving zerovalent copper metal." @default.
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- W1980239816 date "2010-02-15" @default.
- W1980239816 modified "2023-10-01" @default.
- W1980239816 title "Mechanistic Insights into Copper(I)-Catalyzed Azide-Alkyne Cycloadditions using Continuous Flow Conditions" @default.
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- W1980239816 doi "https://doi.org/10.1002/adsc.200900726" @default.
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