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- W1980302476 abstract "The synthesis of stilbenoids and styryl carboxylic acids is accomplished with high E-stereoselectivity by olefination of aldehydes with thiophthalides under basic conditions. The olefination is highly atom-efficient as it only loses elemental sulfur during the reaction. This olefination, in conjunction with retro Kolbe–Schmitt reaction, allows facile synthesis of E-hydroxystilbenoids with minimal employment of protecting groups. This study also discloses two important findings: formation of i) 4-methylsulfanyl isocoumarins and ii) an 2-arylindenone." @default.
- W1980302476 created "2016-06-24" @default.
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- W1980302476 date "2012-01-01" @default.
- W1980302476 modified "2023-09-25" @default.
- W1980302476 title "Stereoselective synthesis of hydroxy stilbenoids and styrenes by atom-efficient olefination with thiophthalides" @default.
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- W1980302476 doi "https://doi.org/10.1039/c2ob06991a" @default.
- W1980302476 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22362491" @default.
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