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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1980317634> ?p ?o ?g. }

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• W1980317634 abstract "Photoisomerization of two carbocyanine derivatives has been examined in bis(2-ethylhexyl) sodium sulfosuccinate (AOT) reverse micelles to understand the factors that govern this process in the interfacial region of organized assemblies. To this effect, fluorescence lifetimes and quantum yields of 3,3(')-diethyloxadicarbocyanine iodide and merocyanine 540 have been measured in AOT∕isooctane∕water and AOT∕cyclohexane∕water reverse micellar systems as a function of the mole ratio of water to the surfactant, W. The nonradiative rate constants, which have been identified as the rates of photoisomerization for these solutes, were obtained from the experimentally measured parameters. The steady rise and subsequent saturation observed in the nonradiative rate constants upon increasing W has been rationalized in terms of micellar packing. An inverse correlation has been obtained between the nonradiative rate constants and the critical packing parameter, indicating that the interfacial friction experienced by the solute molecule is essentially described by this parameter." @default.
• W1980317634 created "2016-06-24" @default.
• W1980317634 creator A5025983344 @default.
• W1980317634 creator A5041404847 @default.
• W1980317634 date "2011-01-14" @default.
• W1980317634 modified "2023-09-27" @default.
• W1980317634 title "Characterizing interfacial friction in bis(2-ethylhexyl) sodium sulfosuccinate reverse micelles from photoisomerization studies of carbocyanine derivatives" @default.
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• W1980317634 doi "https://doi.org/10.1063/1.3529013" @default.
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