Matches in SemOpenAlex for { <https://semopenalex.org/work/W1980338816> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W1980338816 endingPage "120" @default.
- W1980338816 startingPage "114" @default.
- W1980338816 abstract "The absorption spectra of trinitrophenyl derivatives of poly(L-lysine) and L-asparaginase undergo irreversible changes in the presence of KBH4. The spectra of trinitrophenyl derivatives of N-acetyl-L-lysine and N-acetyl-L-cysteine are also affected by the addition of the reducing agent. A broad absorption band with a maximum at 426 nm appears in the presence of low concentrations of borohydride with a concomitant decrease in absorbance of the 346 nm band which is characteristic of 1-substituted 2,4,6-trinitrophenyl compounds. In the presence of higher concentrations of KBH4 the long wavelength band becomes less broad as the maximum is shifted to 410 nm and the 346 nm band completely disappears. Similar spectral changes were observed in the presence of Na2SO3 although these were reversible upon removal of the sulfite by dialysis. Based on the spectral similarities with sulfite and hydroxide adducts, we suggest that the 426 nm maximum represents a 1:1 adduct formed between the trinitrophenyl moiety and a hydride ion while the band at 410 nm is assigned to the 1:2 adduct." @default.
- W1980338816 created "2016-06-24" @default.
- W1980338816 creator A5018016251 @default.
- W1980338816 creator A5073943378 @default.
- W1980338816 date "1977-03-01" @default.
- W1980338816 modified "2023-09-24" @default.
- W1980338816 title "A spectrophotometric study of the reaction of borohydride with trinitrophenyl derivatives of amino acids and proteins" @default.
- W1980338816 cites W1494095650 @default.
- W1980338816 cites W1514423438 @default.
- W1980338816 cites W1517172699 @default.
- W1980338816 cites W1544499572 @default.
- W1980338816 cites W1560012114 @default.
- W1980338816 cites W1564838675 @default.
- W1980338816 cites W1877845887 @default.
- W1980338816 cites W1979065213 @default.
- W1980338816 cites W2956051361 @default.
- W1980338816 doi "https://doi.org/10.1016/0005-2795(77)90046-0" @default.
- W1980338816 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/849452" @default.
- W1980338816 hasPublicationYear "1977" @default.
- W1980338816 type Work @default.
- W1980338816 sameAs 1980338816 @default.
- W1980338816 citedByCount "5" @default.
- W1980338816 crossrefType "journal-article" @default.
- W1980338816 hasAuthorship W1980338816A5018016251 @default.
- W1980338816 hasAuthorship W1980338816A5073943378 @default.
- W1980338816 hasConcept C108204754 @default.
- W1980338816 hasConcept C119824511 @default.
- W1980338816 hasConcept C120665830 @default.
- W1980338816 hasConcept C121332964 @default.
- W1980338816 hasConcept C125287762 @default.
- W1980338816 hasConcept C13965031 @default.
- W1980338816 hasConcept C153642686 @default.
- W1980338816 hasConcept C155647269 @default.
- W1980338816 hasConcept C159985019 @default.
- W1980338816 hasConcept C161790260 @default.
- W1980338816 hasConcept C178790620 @default.
- W1980338816 hasConcept C179104552 @default.
- W1980338816 hasConcept C185592680 @default.
- W1980338816 hasConcept C191274033 @default.
- W1980338816 hasConcept C192562407 @default.
- W1980338816 hasConcept C2776568683 @default.
- W1980338816 hasConcept C2778931688 @default.
- W1980338816 hasConcept C2779830873 @default.
- W1980338816 hasConcept C43617362 @default.
- W1980338816 hasConcept C62520636 @default.
- W1980338816 hasConcept C75473681 @default.
- W1980338816 hasConcept C98015330 @default.
- W1980338816 hasConceptScore W1980338816C108204754 @default.
- W1980338816 hasConceptScore W1980338816C119824511 @default.
- W1980338816 hasConceptScore W1980338816C120665830 @default.
- W1980338816 hasConceptScore W1980338816C121332964 @default.
- W1980338816 hasConceptScore W1980338816C125287762 @default.
- W1980338816 hasConceptScore W1980338816C13965031 @default.
- W1980338816 hasConceptScore W1980338816C153642686 @default.
- W1980338816 hasConceptScore W1980338816C155647269 @default.
- W1980338816 hasConceptScore W1980338816C159985019 @default.
- W1980338816 hasConceptScore W1980338816C161790260 @default.
- W1980338816 hasConceptScore W1980338816C178790620 @default.
- W1980338816 hasConceptScore W1980338816C179104552 @default.
- W1980338816 hasConceptScore W1980338816C185592680 @default.
- W1980338816 hasConceptScore W1980338816C191274033 @default.
- W1980338816 hasConceptScore W1980338816C192562407 @default.
- W1980338816 hasConceptScore W1980338816C2776568683 @default.
- W1980338816 hasConceptScore W1980338816C2778931688 @default.
- W1980338816 hasConceptScore W1980338816C2779830873 @default.
- W1980338816 hasConceptScore W1980338816C43617362 @default.
- W1980338816 hasConceptScore W1980338816C62520636 @default.
- W1980338816 hasConceptScore W1980338816C75473681 @default.
- W1980338816 hasConceptScore W1980338816C98015330 @default.
- W1980338816 hasIssue "1" @default.
- W1980338816 hasLocation W19803388161 @default.
- W1980338816 hasLocation W19803388162 @default.
- W1980338816 hasOpenAccess W1980338816 @default.
- W1980338816 hasPrimaryLocation W19803388161 @default.
- W1980338816 hasRelatedWork W1980338816 @default.
- W1980338816 hasRelatedWork W2000031697 @default.
- W1980338816 hasRelatedWork W2046518989 @default.
- W1980338816 hasRelatedWork W2072233889 @default.
- W1980338816 hasRelatedWork W2104233005 @default.
- W1980338816 hasRelatedWork W2163046103 @default.
- W1980338816 hasRelatedWork W2353529355 @default.
- W1980338816 hasRelatedWork W2355766673 @default.
- W1980338816 hasRelatedWork W77116797 @default.
- W1980338816 hasRelatedWork W2093258893 @default.
- W1980338816 hasVolume "491" @default.
- W1980338816 isParatext "false" @default.
- W1980338816 isRetracted "false" @default.
- W1980338816 magId "1980338816" @default.
- W1980338816 workType "article" @default.