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- W1980354369 abstract "Abstract Ammonium thiosulfate (ATS) is a popular liquid fertilizer in North America, and potassium thiosulfate (KTS) is also gaining acceptance for specialty purposes. Thiosulfate is known to oxidize rapidly in soil to tetrathionate and then to sulfate, but little information is available on the effect of temperature on these reactions. The objective of this study was to compare the rates of thiosulfate oxidation at three temperatures (5, 15, 25°C) by three soils, an Enon loamy sand from North Carolina (soil NC), an O'Neill loamy sand from Nebraska (soil NE), and a Vang loam from North Dakota (soil ND). Ammonium thiosulfate, or KTS were added at a rate of 25 mg S kg−1. At 25°C, oxidation was very rapid, being complete after 1 or 2 weeks by all three soils. No apparent immobilization of the applied S was observed with any soil after 2 weeks of incubation. At 15°C, oxidation was slowed, but oxidation was still nearly complete after 2 or 3 weeks. There was some apparent S immobilization by soil NE, and to a lesser degree by soil ND at this temperature. At 5°C, the kinetics of oxidation and immobilization differed greatly between soils. With soil NC, oxidation was complete after 4 weeks, with no apparent immobilization. Soil NE exhibited a strong immobilization of the added S at 5°C, with most of the applied S remaining immobilized for 12 weeks. Soil ND was intermediate between these two soils, showing a temporary immobilization of applied thiosulfate for 2–6 weeks, with apparent mineralization from 6–12 weeks. The effect of temperature on immobilization of S fertilizers deserves further research. Acknowledgments The authors thank John Clapp and Charles Shapiro for providing the Enon and O'Neill soils, respectively. The authors thank Tessenderlo-Kerley for providing financial support of this study." @default.
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- W1980354369 date "2001-10-31" @default.
- W1980354369 modified "2023-10-09" @default.
- W1980354369 title "Thiosulfate oxidation by three soils as influenced by temperature" @default.
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- W1980354369 doi "https://doi.org/10.1081/css-120000966" @default.
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