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- W1980360001 abstract "Interactions of ${mathrm{Li}}^{+}$ and ${mathrm{Na}}^{+}$ with ${mathrm{C}}_{60}$ molecules have been studied over the collision energy range from 0 to 150 eV. We observe insertion of the alkali-metal ions to form the endohedral [${mathrm{LiC}}_{60}$${]}^{+}$ and [${mathrm{NaC}}_{60}$${]}^{+}$ species, with energy thresholds of 6 and 20 eV, respectively. At higher collision energies, the excited [${mathrm{NaC}}_{60}$${]}^{+}$ appears to relax mainly by loss of ${mathrm{C}}_{2}$ units from the fullerene cage, yielding [${mathrm{NaC}}_{60mathrm{ensuremath{-}}2mathit{n}}$${]}^{+}$. For [${mathrm{LiC}}_{60}$${]}^{+}$, escape of the ${mathrm{Li}}^{+}$ competes effectively with ${mathrm{C}}_{2}$ loss. For both ${mathrm{Li}}^{+}$ and ${mathrm{Na}}^{+}$, the signal for pure carbon fragment ions ${mathrm{C}}_{60mathrm{ensuremath{-}}2mathit{n}}^{+}$ increases sharply at ensuremath{sim}30 eV, which is attributed to thermionic emission." @default.
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- W1980360001 date "1992-08-31" @default.
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- W1980360001 doi "https://doi.org/10.1103/physrevlett.69.1352" @default.
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