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- W1980363014 abstract "Abstract Reaction of trans -1,2-[diethylaluminium]stilbene with lithium in polar solvents results in the metallation of both ortho -positions. It is shown that the reaction is accompanied by migration of the Et 2 Al-group from the vinyl to the ortho -position, whereby trans -1,2-dilithium- o , o ′-[diethylaluminium]stilbene is formed. The mechanism is discussed. In polaren Losungsmitteln reagiert trans -1,2-[Diethylaluminium]stilben mit Lithium unter Metallierung der beiden ortho -Positionen. Es wird gezeigt, dass die Umsetzung mit einem Platzwechsel der Et 2 Al-Gruppen aus den vinyl- in die ortho -Stellungen begleitet ist, wobei trans -1,2-Dilithium- o , o ′-[diethylaluminium]- stilben entsteht. Der Mechanismus wird diskutiert." @default.
- W1980363014 created "2016-06-24" @default.
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- W1980363014 date "1978-03-01" @default.
- W1980363014 modified "2023-10-02" @default.
- W1980363014 title "ortho-Metallierung vontrans-1,2-[diethylaluminium]stilben" @default.
- W1980363014 cites W2131609169 @default.
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- W1980363014 doi "https://doi.org/10.1016/s0022-328x(00)90943-4" @default.
- W1980363014 hasPublicationYear "1978" @default.
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