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• W1980379720 endingPage "11145" @default.
• W1980379720 startingPage "11137" @default.
• W1980379720 abstract "In Part 1 of this two-part series of papers, phase abundances, lattice parameters, crystallite sizes, and microstructures of three series of AB2-based metal hydride alloys were studied. The base alloys with B/A stoichiometry of 2.0 in series 177, 190, and 193 are rich in C14, equal in C14/C15, and rich in C15 phases, respectively. In each series of alloys, the B/A stoichiometry varies from 1.8, 1.9, 2.0, 2.1, to 2.2. The effects of varying B/A stoichiometry to microstructures are the same for these three series of alloys. As the alloy formula changes from AB1.8, AB1.9, AB2.0, AB2.1, to AB2.2, the following events occur: C14-to-C15 phase ratio decreases, both C14 and TiNi secondary phase lattice parameters and unit cell volume reduce; the a/c aspect ratio of C14 phase first decreases and then increases; abundances of non-Laves secondary phases decrease; and the Zr/Ti ratio in AB phase decreases. The C14/C15 ratio is closely related to the average electron density with a threshold that first decreases from 7.13 (AB1.8) to 7.08 (AB1.9) and to 7.06 (AB2.0) and then increases to 7.08 (AB2.1) and 7.09 (AB2.2) as the stoichiometry increases. The distributions of B-site elements are not uniform with most of the V, Cr, Mn, Co residing in AB2 phase and Sn in Zr7Ni10 phase." @default.
• W1980379720 created "2016-06-24" @default.
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• W1980379720 date "2011-08-01" @default.
• W1980379720 modified "2023-10-04" @default.
• W1980379720 title "Studies of off-stoichiometric AB2 metal hydride alloy: Part 1. Structural characteristics" @default.
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• W1980379720 doi "https://doi.org/10.1016/j.ijhydene.2011.05.057" @default.
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