Matches in SemOpenAlex for { <https://semopenalex.org/work/W1980411016> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W1980411016 endingPage "390" @default.
- W1980411016 startingPage "386" @default.
- W1980411016 abstract "덴드리머의 중심에 삼발이 핵을 갖는 덴드리머의 합성을 위한 효율적인 연결 방법이 개발되었다. 합성전략은 알데히드 덴드론과 아자이드기를 갖는 삼발이 핵 사이의 반응을 톨루엔 용매와 triphenylphosphine 존재하에서 진행하는 새로운 클릭화학(Staudinger/aza-Wittig 반응)을 이용하였다. 덴드리머의 삼발이 핵으로 작용할 수 있는 단위체인 1,3,5-tris-(3-azido-propoxy)-benzene을 합성하였고, 이 화합물의 아자이드기는 덴드리머의 형성에 이용되었다. 1,3,5-Tris-(3-azido-propoxy)-benzene을 이용하여 알데히드 덴드론과 Staudinger/aza-Wittig 반응을 통해 덴드리머를 합성하였으며, 모든 덴드리머는 높은 수득률로 얻어졌다. Efficient stitching methods for the synthesis of tripodal Fr<TEX>$acute{e}$</TEX>chet-type dendrimers containing secondary amine as a connector were elaborated. The synthetic strategy involved Staudinger/aza-Wittig reactions (new click reaction) between tripodal tris(azides) and aldehyde-dendrons in toluene in the presence of triphenylphosphine and followed by the reduction of imine intermediates. The tripodal core (1,3,5-tris-(3-azido-propoxy)-benzene) was chosen to serve as the azide functionalities for dendrimer growth. 1,3,5-Tris-(3-azido-propoxy)-benzene was stitched with the aldehyde-functionalized Fr<TEX>$acute{e}$</TEX>chet-type dendrons via Staudinger/aza-Wittig reactions leading to the formation of the corresponding Fr<TEX>$acute{e}$</TEX>chet-type dendrimers in high yields." @default.
- W1980411016 created "2016-06-24" @default.
- W1980411016 creator A5002077293 @default.
- W1980411016 creator A5060874168 @default.
- W1980411016 creator A5079305414 @default.
- W1980411016 date "2014-05-25" @default.
- W1980411016 modified "2023-10-03" @default.
- W1980411016 title "Synthesis of Fréchet-type Dendrimers with Tripodal Core via Staudinger/Aza-Wittig Reactions" @default.
- W1980411016 cites W142012613 @default.
- W1980411016 cites W1623423921 @default.
- W1980411016 cites W1968453824 @default.
- W1980411016 cites W1971698744 @default.
- W1980411016 cites W1980627211 @default.
- W1980411016 cites W2011572869 @default.
- W1980411016 cites W2017394448 @default.
- W1980411016 cites W2019660049 @default.
- W1980411016 cites W2028617731 @default.
- W1980411016 cites W2034757194 @default.
- W1980411016 cites W2038106135 @default.
- W1980411016 cites W2050117247 @default.
- W1980411016 cites W2068154015 @default.
- W1980411016 cites W2073500340 @default.
- W1980411016 cites W2073731776 @default.
- W1980411016 cites W2078020141 @default.
- W1980411016 cites W2079003266 @default.
- W1980411016 cites W2100819784 @default.
- W1980411016 cites W2104507253 @default.
- W1980411016 cites W2137275115 @default.
- W1980411016 cites W2144823092 @default.
- W1980411016 cites W2172879115 @default.
- W1980411016 cites W281018712 @default.
- W1980411016 cites W2949297514 @default.
- W1980411016 cites W2950322869 @default.
- W1980411016 cites W425388278 @default.
- W1980411016 cites W903926595 @default.
- W1980411016 doi "https://doi.org/10.7317/pk.2014.38.3.386" @default.
- W1980411016 hasPublicationYear "2014" @default.
- W1980411016 type Work @default.
- W1980411016 sameAs 1980411016 @default.
- W1980411016 citedByCount "0" @default.
- W1980411016 crossrefType "journal-article" @default.
- W1980411016 hasAuthorship W1980411016A5002077293 @default.
- W1980411016 hasAuthorship W1980411016A5060874168 @default.
- W1980411016 hasAuthorship W1980411016A5079305414 @default.
- W1980411016 hasBestOaLocation W19804110161 @default.
- W1980411016 hasConcept C161790260 @default.
- W1980411016 hasConcept C178790620 @default.
- W1980411016 hasConcept C185592680 @default.
- W1980411016 hasConcept C188027245 @default.
- W1980411016 hasConcept C21951064 @default.
- W1980411016 hasConcept C24292678 @default.
- W1980411016 hasConcept C2776573223 @default.
- W1980411016 hasConcept C2776730309 @default.
- W1980411016 hasConcept C2777247709 @default.
- W1980411016 hasConcept C2777691172 @default.
- W1980411016 hasConcept C2779825165 @default.
- W1980411016 hasConcept C2780997848 @default.
- W1980411016 hasConcept C2781014771 @default.
- W1980411016 hasConcept C55493867 @default.
- W1980411016 hasConcept C55637122 @default.
- W1980411016 hasConceptScore W1980411016C161790260 @default.
- W1980411016 hasConceptScore W1980411016C178790620 @default.
- W1980411016 hasConceptScore W1980411016C185592680 @default.
- W1980411016 hasConceptScore W1980411016C188027245 @default.
- W1980411016 hasConceptScore W1980411016C21951064 @default.
- W1980411016 hasConceptScore W1980411016C24292678 @default.
- W1980411016 hasConceptScore W1980411016C2776573223 @default.
- W1980411016 hasConceptScore W1980411016C2776730309 @default.
- W1980411016 hasConceptScore W1980411016C2777247709 @default.
- W1980411016 hasConceptScore W1980411016C2777691172 @default.
- W1980411016 hasConceptScore W1980411016C2779825165 @default.
- W1980411016 hasConceptScore W1980411016C2780997848 @default.
- W1980411016 hasConceptScore W1980411016C2781014771 @default.
- W1980411016 hasConceptScore W1980411016C55493867 @default.
- W1980411016 hasConceptScore W1980411016C55637122 @default.
- W1980411016 hasIssue "3" @default.
- W1980411016 hasLocation W19804110161 @default.
- W1980411016 hasOpenAccess W1980411016 @default.
- W1980411016 hasPrimaryLocation W19804110161 @default.
- W1980411016 hasRelatedWork W1980411016 @default.
- W1980411016 hasRelatedWork W2006586323 @default.
- W1980411016 hasRelatedWork W2017394448 @default.
- W1980411016 hasRelatedWork W2156764750 @default.
- W1980411016 hasRelatedWork W2363331259 @default.
- W1980411016 hasRelatedWork W2373548687 @default.
- W1980411016 hasRelatedWork W2743679969 @default.
- W1980411016 hasRelatedWork W2909492667 @default.
- W1980411016 hasRelatedWork W2949738464 @default.
- W1980411016 hasRelatedWork W3189709349 @default.
- W1980411016 hasVolume "38" @default.
- W1980411016 isParatext "false" @default.
- W1980411016 isRetracted "false" @default.
- W1980411016 magId "1980411016" @default.
- W1980411016 workType "article" @default.