Matches in SemOpenAlex for { <https://semopenalex.org/work/W1980412755> ?p ?o ?g. }
- W1980412755 abstract "The results of spectrophotometric and conductimetric studies of the ionization of several phenol derivatives in the presence of amines in dioxane and aqueous dioxane solutions, were used to delineate the ranges of solvent polarity over which 1:1 proton transfer complexes are formed. Increasing polarity favors the formation of proton transfer complexes up to a point determined by the nature of the acid-base pair. Proton transfer complexes display a measurable stability over an appreciable range of solvent polarity varying from low (D < 11) to medium (11 < D < 45). Their formation involves a free energy change ranging from −2.0 to −7.1 kcal · mole−1 and a decrease in enthalpy ranging from 6.1 to 16.8 kcal · mole−1. The effects of proton transfer complex formation between side chain groups of biopolymers are subdivided into structural, chemical and kinetic, and the relevance of the results obtained from model studies to biopolymers is discussed. It is suggested that formation of proton transfer complexes can affect the direction of conformational change in macromolecules and play an important role in the formation of oligomeric structures. The numerical inferiority of proton transfer complexes in biopolymers, relative to hydrophobic and hydrogen bonding interactions should be partially offset by the greater contribution of the former to the total free energy and enthalpy of formation of specific biopolymer conformations." @default.
- W1980412755 created "2016-06-24" @default.
- W1980412755 creator A5056479587 @default.
- W1980412755 creator A5057788067 @default.
- W1980412755 creator A5090257767 @default.
- W1980412755 date "1970-07-01" @default.
- W1980412755 modified "2023-09-26" @default.
- W1980412755 title "Models of intermolecular interactions involving proton transfer in biopolymers" @default.
- W1980412755 cites W1497457065 @default.
- W1980412755 cites W1501262730 @default.
- W1980412755 cites W1558814513 @default.
- W1980412755 cites W157808733 @default.
- W1980412755 cites W1964350611 @default.
- W1980412755 cites W1966777147 @default.
- W1980412755 cites W1967427912 @default.
- W1980412755 cites W1968605857 @default.
- W1980412755 cites W1970611088 @default.
- W1980412755 cites W1972430165 @default.
- W1980412755 cites W1973181401 @default.
- W1980412755 cites W1976951969 @default.
- W1980412755 cites W1983363016 @default.
- W1980412755 cites W1984463687 @default.
- W1980412755 cites W2000629427 @default.
- W1980412755 cites W2001929545 @default.
- W1980412755 cites W2002977794 @default.
- W1980412755 cites W2005353981 @default.
- W1980412755 cites W2014947510 @default.
- W1980412755 cites W2018216217 @default.
- W1980412755 cites W2021590633 @default.
- W1980412755 cites W2027184218 @default.
- W1980412755 cites W2028538783 @default.
- W1980412755 cites W2043290803 @default.
- W1980412755 cites W2046399589 @default.
- W1980412755 cites W2050438184 @default.
- W1980412755 cites W2054699060 @default.
- W1980412755 cites W2056144602 @default.
- W1980412755 cites W2066771090 @default.
- W1980412755 cites W2073198049 @default.
- W1980412755 cites W2074496353 @default.
- W1980412755 cites W2078237917 @default.
- W1980412755 cites W2078798877 @default.
- W1980412755 cites W2085504828 @default.
- W1980412755 cites W2112157184 @default.
- W1980412755 cites W2127400370 @default.
- W1980412755 cites W2158268893 @default.
- W1980412755 cites W2160804892 @default.
- W1980412755 cites W2312226682 @default.
- W1980412755 cites W2312261339 @default.
- W1980412755 cites W2316602502 @default.
- W1980412755 cites W2317848611 @default.
- W1980412755 cites W2318051838 @default.
- W1980412755 cites W2318689160 @default.
- W1980412755 cites W2319505035 @default.
- W1980412755 cites W2319779224 @default.
- W1980412755 cites W2320315768 @default.
- W1980412755 cites W2321972685 @default.
- W1980412755 cites W2323942512 @default.
- W1980412755 cites W2324563020 @default.
- W1980412755 cites W2326639051 @default.
- W1980412755 cites W2326886902 @default.
- W1980412755 cites W2327983296 @default.
- W1980412755 cites W2329809445 @default.
- W1980412755 cites W2330013523 @default.
- W1980412755 cites W2330057124 @default.
- W1980412755 cites W2331039679 @default.
- W1980412755 cites W2333344828 @default.
- W1980412755 cites W2333387796 @default.
- W1980412755 cites W2333999412 @default.
- W1980412755 cites W2334702016 @default.
- W1980412755 cites W2433608909 @default.
- W1980412755 cites W2035659916 @default.
- W1980412755 cites W2094643986 @default.
- W1980412755 doi "https://doi.org/10.1016/0005-2795(70)90065-6" @default.
- W1980412755 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/5488951" @default.
- W1980412755 hasPublicationYear "1970" @default.
- W1980412755 type Work @default.
- W1980412755 sameAs 1980412755 @default.
- W1980412755 citedByCount "11" @default.
- W1980412755 crossrefType "journal-article" @default.
- W1980412755 hasAuthorship W1980412755A5056479587 @default.
- W1980412755 hasAuthorship W1980412755A5057788067 @default.
- W1980412755 hasAuthorship W1980412755A5090257767 @default.
- W1980412755 hasConcept C112887158 @default.
- W1980412755 hasConcept C121332964 @default.
- W1980412755 hasConcept C147789679 @default.
- W1980412755 hasConcept C1491633281 @default.
- W1980412755 hasConcept C166950319 @default.
- W1980412755 hasConcept C178790620 @default.
- W1980412755 hasConcept C184651966 @default.
- W1980412755 hasConcept C185592680 @default.
- W1980412755 hasConcept C204389451 @default.
- W1980412755 hasConcept C2777361361 @default.
- W1980412755 hasConcept C2780471494 @default.
- W1980412755 hasConcept C3288061 @default.
- W1980412755 hasConcept C32909587 @default.
- W1980412755 hasConcept C54516573 @default.
- W1980412755 hasConcept C55493867 @default.
- W1980412755 hasConcept C62520636 @default.
- W1980412755 hasConcept C8010536 @default.
- W1980412755 hasConcept C97355855 @default.