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• W1980420159 abstract "The far infrared (fir) reflection spectra of the hexachalcogenohypodiphosphates M2P2X6 (M = Mg, Cd, Mn, Fe, Co, Ni, Pb, Sn; X = S, Se) have been studied. TOLO splittings are determined from Kramers-Kronig analyses, the splitting is large for the lattice vibration modes of ferroelectric Sn2P2S6 but very small for Ni2P2S6. Measurements with polarized light permit an assignment of the A2u and Eu modes of the ethane like P2S6 units in Mn2P2S6. Factor group analyses were performed for all hitherto described hexachalcogenohypodiphosphates. The fir absorption spectra of the less symmetric compounds Hg2P2S6, Hg2P2Se6, Ca2P2S6, TiP2S6, In43P2S6, In43P2Se6, and CuCrP2S6 are given." @default.
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• W1980420159 date "1984-01-01" @default.
• W1980420159 modified "2023-09-24" @default.
• W1980420159 title "Far infrared spectra of hexachalcogenohypodiphosphates" @default.
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• W1980420159 doi "https://doi.org/10.1016/0022-4596(84)90322-0" @default.
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