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• W1980423077 endingPage "143" @default.
• W1980423077 startingPage "135" @default.
• W1980423077 abstract "The complex Ir(CH3) (CO) (CF3SO3)2 (dppe) (1) has been synthesized from the reaction of Ir(CH3)I2(CO) (dppe) and silver triflate. Methane and IrH(CO) (CF3SO3)2 (dppe) (2) are formed when a methylene chloride solution of 1 is placed under 760 torr dihydrogen. Conductivity studies indicate that methylene chloride solutions of complexes 1 and 2 are weak electrolytes and only partially ionized at concentrations above 1 mM. Complex 2 is an effective hydrogenation catalyst for ethylene and 1-hexene while acetone hydrogenation is inhibited by the formation of [IrH2(HOCH(CH3)2) (CO) (dppe)] (OTf) (3). Linear dimerization and polymerization of styrene occurs via a carbocationic mechanism initiated by triflic acid elimination from 2. Treatment of an acetonitrile solution of Ir(CH3)I2(CO) (dppe) with silver hexafluorophosphate produces the solvent promoted carbonyl insertion product [Ir(C(O)CH3) (NCCH3)3 (dppe)] [PF6]2 (7) which readily undergoes deinsertion in methylene chloride to form [Ir(CH3) (CO) (NCCH3)2 (dppe)] [PF6]2 (8) and acetonitrile." @default.
• W1980423077 created "2016-06-24" @default.
• W1980423077 creator A5006844227 @default.
• W1980423077 creator A5025309595 @default.
• W1980423077 date "1995-12-01" @default.
• W1980423077 modified "2023-09-25" @default.
• W1980423077 title "The synthesis and reactivity of electrophilic iridium (III) complexes containing bis (diphenylphosphino) ethane" @default.
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• W1980423077 doi "https://doi.org/10.1016/0020-1693(95)04527-9" @default.
• W1980423077 hasPublicationYear "1995" @default.
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