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- W1980427047 abstract "The cationic Ir(I) complex [{Ir(bis(pyrazol-1-yl)methane)(CO)2}BPh4] (1) catalyzes the hydroamination of 4-pentyn-1-amine to form 2-methylpyrroline and subsequent hydrosilation to form 1-(triethylsilyl)-2-methylpyrrolidine in a one-pot, tandem procedure in a short time frame and with essentially quantitative yields. The tandem transformation can also be achieved using the related Ir(I) complex [{Ir(bis(1-methylimidazol-2-yl)methane)(CO)2}BPh4] (2) as catalyst." @default.
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- W1980427047 date "2003-09-25" @default.
- W1980427047 modified "2023-10-16" @default.
- W1980427047 title "One-Pot Tandem Hydroamination/Hydrosilation Catalyzed by Cationic Iridium(I) Complexes" @default.
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- W1980427047 doi "https://doi.org/10.1021/om034004z" @default.
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