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• W1980439902 abstract "A study of two prewaves of the Ni(II)-SCN - system was carried out under the experimental conditions when the influence of electroreduction of SCN - is negligible. Kinetics of Ni(II) reduction in thiocyanate media on the dropping mercury electrode was studied by DC Tast Polarography (DC T P) via determination of Koutecký's parameter χ; the influence of different variables was analyzed. The study of prewaves was performed using various polarographic techniques. Values of χ depend on the SCN - concentration, pH, ionic strength (Ψ-effect) and on the nature of the supporting electrolyte. The number of electrons n , the transfer coefficient α, the stoichiometric number ν, ∆ H ≠ , and ∆ S ≠ were determined (compensation effect). The first prewave has character of a reaction in the solution, the second prewave is a surface process. Main features of both mechanisms are common: catalytic nature, one-electron step discharge and the rate-determining process between species of opposite charges." @default.
• W1980439902 created "2016-06-24" @default.
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• W1980439902 date "2000-01-01" @default.
• W1980439902 modified "2023-09-27" @default.
• W1980439902 title "Analysis of the Electrode Kinetics of Ni(II) Reduction in Thiocyanate Media on the Dropping Mercury Electrode" @default.
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• W1980439902 doi "https://doi.org/10.1135/cccc20000326" @default.
• W1980439902 hasPublicationYear "2000" @default.
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